User:Graeme Bartlett/antimonide iodide
Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide chlorides, antimonide iodides, phosphide iodides, and arsenide iodides.
List[edit]
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Thioantimonate iodides[edit]
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| (LiI)2Li3SbS3 | orthorhombic | Pnnm | a = 10.436, b = 13.509, c = 7.530 Z = 4 | 1061.6 | pale yellow; air+water sensitive | [1] | |
| (CuI)2Cu3SbS3 | orthorhombic | Pnnm | a = 10.488, b = 12.619, c = 7.316 Z = 4 | 968.2 | red orange | [2] | |
| (AgI)2Ag3SbS3 | orthorhombic | Pnnm | a = 10.9674, b = 13.520, c = 7.7460, Z = 4 | 1156.3 | pale yellow | [3] | |
| Sn2SbS2I3 | [4] | ||||||
| Pb2SbS2I3 | orthorhombic | Cmcm | a = 4.3262, b = 14.181, c = 16.556 Z=4 | 1017.7 | room temperature | [4] |
Selenoantimonate iodides[edit]
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| MnSbSe2I | monoclinic | C2/m | a = 13.319 b = 4.0359 c = 10.105 β = 91.27 | [5] | |||
| [3] | |||||||
| Sn2SbSe2I3 | [4] |
References[edit]
- ^ Pfitzner, Arno; Preitschaft, Christian; Rau, Franz (January 2004). "(LiI)2Li3SbS3: A mixed Alkali Metal Halide Thioantimonate with a novel Tetrahedron Network". Zeitschrift für anorganische und allgemeine Chemie (in German). 630 (1): 75–79. doi:10.1002/zaac.200300292. ISSN 0044-2313.
- ^ Pfitzner, Arno (December 1997). "(CuI)2Cu3SbS3: Copper Iodide as Solid Solvent for Thiometalate ions". Chemistry - A European Journal (in German). 3 (12): 2032–2038. doi:10.1002/chem.19970031218.
- ^ a b Nilges, Tom; Reiser, Sara; Hong, Jung Hoon; Gaudin, Etienne; Pfitzner, Arno (2002). "Preparation, structural, Raman and impedance spectroscopic characterisation of the silver ion conductor (AgI) 2 Ag 3 SbS 3". Phys. Chem. Chem. Phys. 4 (23): 5888–5894. doi:10.1039/B203556A. ISSN 1463-9076.
- ^ a b c Doussier, Charlotte; Moëlo, Yves; Léone, Philippe; Meerschaut, Alain; Evain, Michel (September 2007). "Crystal structure of Pb2SbS2I3, and re-examination of the crystal chemistry within the group of (Pb/Sn/Sb) chalcogeno-iodides". Solid State Sciences. 9 (9): 792–803. Bibcode:2007SSSci...9..792D. doi:10.1016/j.solidstatesciences.2007.07.003.
- ^ Tougait, Olivier; Ibers, James A.; Mar, Arthur (2003-08-15). "Manganese antimony diselenide iodide, MnSbSe 2 I". Acta Crystallographica Section C Crystal Structure Communications. 59 (8): i77–i78. doi:10.1107/S0108270103014082. ISSN 0108-2701. PMID 12909744.