User:Graeme Bartlett/acetate borate
Acetate borates are mixed anion compounds that contain both acetate and borate ions.
Borate enhances the thermal stability for acetates.
List[edit]
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| R3c | |||||||
| [ZnAc]·[ZnBO3] | orthorhombic | P212121 | a=4.9500 b=8.593 c=14.607 Z=4 | 621.3 | 2.658 | stable up to 540°C | [1] |
| pz = pyrazolyl {[HB(pz)3]2Y(μ-O2CCH3)}2 | [2] | ||||||
| {[HB(pz)3]Y(μ-O2CCH3)2}2 | a=10.945 b=7.876 c=24.498 β=98.50° Z=4 | 2088 | [2] | ||||
| Y2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 | monoclinic | C2/c | a =19.1440 b =8.5429 c =17.2441 β =105.945° | [3] | |||
| La2(CH3CO2)2[B5O9(OH)]·H2O | monoclinic | Cc | a 10.7704 b 20.147 c 6.4727 β 90.582° | 2.975 | SHG 2.0 × KDP | [4] | |
| La2(CH3CO2)2[B5O9(OH)] | monoclinic | Cc | a 10.9596 b 20.263 c 6.4760 β 90.540° | 2.822 | SHG 2.5 × KDP | [4] | |
| Ce2(CH3CO2)2[B5O9(OH)]·H2O | monoclinic | Cc | a 10.7454 b 20.067 c 6.4580 β 90.527° | 3.012 | SHG 1.0 × KDP | [4] | |
| Ce2(CH3CO2)2[B5O9(OH)] | monoclinic | Cc | a 10.9510 b 20.2411 c 6.4535 β 90.494° | [4] | |||
| Pr2(CH3CO2)2[B5O9(OH)]·H2O | monoclinic | Cc | a 10.6897 b 19.988 c 6.4273 β 90.545° | 3.062 | SHG 1.4 × KDP | [4] | |
| Pr2(CH3CO2)2[B5O9(OH)] | monoclinic | Cc | a 10.9265 b 20.2045 c 6.4365 β 90.528° | [4] | |||
| Sm2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 | monoclinic | C2/c | a =19.32 b =8.608 c =17.30 β =105.57° | [3] | |||
| Eu2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 | monoclinic | C2/c | a =19.292 b =8.5902 c =17.291 β =105.64° | [3] | |||
| Gd2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 | monoclinic | C2/c | a =19.218 b =8.5773 c =17.266 β =105.733° | [3] | |||
| Dy2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 | monoclinic | C2/c | a =19.1779 b =8.5481 c =17.2497 β =105.882° | [3] |
References[edit]
- ^ Li, Wei; Deng, Jun-Xia; Pan, Chun-Yang (1 February 2021). "BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]". Inorganic Chemistry. 60 (3): 1289–1293. doi:10.1021/acs.inorgchem.0c02881.
- ^ a b Reger, Daniel L.; Lindeman, Jeffrey A.; Lebioda, Lukasz (1988-11). "Tris(pyrazolyl)borate complexes of yttrium. X-ray crystal structures of [HB(pz)3]2YCl(Hpz) and {[HB(pz)3]Y(.mu.-O2CCH3)2}2 (pz = pyrazolyl ring)". Inorganic Chemistry. 27 (22): 3923–3929. doi:10.1021/ic00295a010. ISSN 0020-1669.
{{cite journal}}: Check date values in:|date=(help) - ^ a b c d e Yang, Hui; Hu, Chun-Li; Mao, Jiang-Gao (2016-06-20). "Ln 2 Ga[B 3 O 6 (OH)] 2 [B 7 O 9 (OH) 2 ](CH 3 CO 2 ) 2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions". Inorganic Chemistry. 55 (12): 6051–6060. doi:10.1021/acs.inorgchem.6b00584. ISSN 0020-1669.
- ^ a b c d e f Yang, Hui; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (2015-08-03). "Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds". Inorganic Chemistry. 54 (15): 7516–7523. doi:10.1021/acs.inorgchem.5b01126. ISSN 0020-1669.